The Resource Advances in physical organic chemistry, Volume 40, editor Richard, J.P, (electronic resource)

Advances in physical organic chemistry, Volume 40, editor Richard, J.P, (electronic resource)

Label
Advances in physical organic chemistry, Volume 40
Title
Advances in physical organic chemistry
Title number
Volume 40
Statement of responsibility
editor Richard, J.P
Contributor
Subject
Genre
Language
  • eng
  • eng
Summary
Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding application from biology to solid state physics
Is Subseries of
Cataloging source
MiAaPQ
Dewey number
  • 547.1082
  • 547.13
Illustrations
illustrations
Index
no index present
Language note
English
LC call number
QD476
LC item number
.A4 2005
Literary form
non fiction
Nature of contents
dictionaries
http://library.link/vocab/relatedWorkOrContributorName
Gold, Victor
Series statement
Advances in physical organic chemistry
Series volume
40
http://library.link/vocab/subjectName
  • Physical organic chemistry
  • Chemistry, Organic
Label
Advances in physical organic chemistry, Volume 40, editor Richard, J.P, (electronic resource)
Instantiates
Publication
Note
Description based upon print version of record
Carrier category
online resource
Carrier category code
cr
Content category
text
Content type code
txt
Contents
  • Cover; Advances in Physical Organic Chemistry; Contents; Editor's preface; Contributors to Volume 40; Carbenes generated within cyclodextrins and zeolites; Introduction; Guest@Host; Definition of guest@host; Supramolecular chemistry; Characterizing the IC; Guests; Neutral organic reaction intermediates; 1,3-Cyclobutadiene; Ortho-benzyne; Carbenes; Hosts; Cyclodextrins; Structure and stoichiometry; Zeolites; Faujasite structure and stoichiometry; Choice of hosts; a- and ß-CyDs; NaY FAU; Objectives; Shape Selectivity; Steering Reaction Outcomes; Control Carbene Spin State
  • Carbene bond angle distortionFacilitate intersystem-crossing; Control Intramolecular Reactions; Constraint; Topologic distortion; Inhibit intermolecular reactions; Limit guest mobility; Supramolecular carbene chemistry; Carbene Reactions; Phase Transfer Catalysis; CyD-mediated Reimer-Tiemann reaction; CyD derivatization using nitrogenous carbene precursors; Encapsulated methylene; Choice of Carbenes; Case Studies; 2-Adamantanylidene; 2-Methylcyclohexanylidene; Evidence for diazo compound intermediacy; No increased C-H insertion into methyl group; Alkene isomer ratio unchanged
  • Cyclooctanylidene3-Nortricyclanylidene; Phenylcarbene; Chloro(phenyl)carbene; Photolysis in alcohol solution; Photolysis in the supramolecular phase; Conclusions; Acknowledgments; References; Mechanistic studies on enzyme-catalyzed phosphoryl transfer; Introduction; Mechanistic Possibilities for Phosphoryl Transfer; Nomenclature Issues; Uncatalyzed reactions of phosphomonoesters; Dianions of Phosphomonoesters; Monoanions of Phosphomonoesters; Uncatalyzed reactions of phosphodiesters; Uncatalyzed reactions of phosphotriesters; Implications for enzymatic catalysis
  • Enzymes that catalyze transfer of the phosphoryl (PO3) groupPhosphatases: General; Alkaline Phosphatase; Acid Phosphatase; Purple Acid Phosphatases; Ser/Thr Protein Phosphatases; Protein-Tyrosine Phosphatases (PTPASES); Ras; Phosphoglucomutases; Phosphodiesterases; Staphylococcal Nuclease; Ribonuclease (RNASE); Phosphotriesterases; References; Finite molecular assemblies in the organic solid state: toward engineering properties of solids; Introduction; Finite molecular assemblies; Supramolecular synthons, finite assemblies, and functional solids; Finite assemblies in the solid state; Synthons
  • Synthetic AssembliesTwo-component assemblies; 1D assemblies; 2D assemblies; 3D assemblies; Functional Assemblies; Two-component assemblies; 1D assemblies; 2D assemblies; 3D assemblies; Our approach: template-controlled solid-state reactivity; Linear Templates; Target-Oriented Syntheses; Summary and outlook; Acknowledgment; References; The physical organic chemistry of very high-spin polyradicals; Introduction; Exchange coupling and magnetism; Preparation and characterization of polyarylmethyl polyradicals; High-spin versus low-spin polyradicals; Diradicals; Triradicals; Tetraradicals
  • Diradical Anions and Diradical Dianions
Dimensions
unknown
Extent
1 online resource (347 p.)
Form of item
online
Isbn
9780080458199
Media category
computer
Media type code
c
Specific material designation
remote
System control number
  • (CKB)1000000000364842
  • (EBL)270124
  • (OCoLC)77236461
  • (SSID)ssj0000099120
  • (PQKBManifestationID)11132945
  • (PQKBTitleCode)TC0000099120
  • (PQKBWorkID)10002432
  • (PQKB)10917604
  • (MiAaPQ)EBC270124
  • (EXLCZ)991000000000364842
Label
Advances in physical organic chemistry, Volume 40, editor Richard, J.P, (electronic resource)
Publication
Note
Description based upon print version of record
Carrier category
online resource
Carrier category code
cr
Content category
text
Content type code
txt
Contents
  • Cover; Advances in Physical Organic Chemistry; Contents; Editor's preface; Contributors to Volume 40; Carbenes generated within cyclodextrins and zeolites; Introduction; Guest@Host; Definition of guest@host; Supramolecular chemistry; Characterizing the IC; Guests; Neutral organic reaction intermediates; 1,3-Cyclobutadiene; Ortho-benzyne; Carbenes; Hosts; Cyclodextrins; Structure and stoichiometry; Zeolites; Faujasite structure and stoichiometry; Choice of hosts; a- and ß-CyDs; NaY FAU; Objectives; Shape Selectivity; Steering Reaction Outcomes; Control Carbene Spin State
  • Carbene bond angle distortionFacilitate intersystem-crossing; Control Intramolecular Reactions; Constraint; Topologic distortion; Inhibit intermolecular reactions; Limit guest mobility; Supramolecular carbene chemistry; Carbene Reactions; Phase Transfer Catalysis; CyD-mediated Reimer-Tiemann reaction; CyD derivatization using nitrogenous carbene precursors; Encapsulated methylene; Choice of Carbenes; Case Studies; 2-Adamantanylidene; 2-Methylcyclohexanylidene; Evidence for diazo compound intermediacy; No increased C-H insertion into methyl group; Alkene isomer ratio unchanged
  • Cyclooctanylidene3-Nortricyclanylidene; Phenylcarbene; Chloro(phenyl)carbene; Photolysis in alcohol solution; Photolysis in the supramolecular phase; Conclusions; Acknowledgments; References; Mechanistic studies on enzyme-catalyzed phosphoryl transfer; Introduction; Mechanistic Possibilities for Phosphoryl Transfer; Nomenclature Issues; Uncatalyzed reactions of phosphomonoesters; Dianions of Phosphomonoesters; Monoanions of Phosphomonoesters; Uncatalyzed reactions of phosphodiesters; Uncatalyzed reactions of phosphotriesters; Implications for enzymatic catalysis
  • Enzymes that catalyze transfer of the phosphoryl (PO3) groupPhosphatases: General; Alkaline Phosphatase; Acid Phosphatase; Purple Acid Phosphatases; Ser/Thr Protein Phosphatases; Protein-Tyrosine Phosphatases (PTPASES); Ras; Phosphoglucomutases; Phosphodiesterases; Staphylococcal Nuclease; Ribonuclease (RNASE); Phosphotriesterases; References; Finite molecular assemblies in the organic solid state: toward engineering properties of solids; Introduction; Finite molecular assemblies; Supramolecular synthons, finite assemblies, and functional solids; Finite assemblies in the solid state; Synthons
  • Synthetic AssembliesTwo-component assemblies; 1D assemblies; 2D assemblies; 3D assemblies; Functional Assemblies; Two-component assemblies; 1D assemblies; 2D assemblies; 3D assemblies; Our approach: template-controlled solid-state reactivity; Linear Templates; Target-Oriented Syntheses; Summary and outlook; Acknowledgment; References; The physical organic chemistry of very high-spin polyradicals; Introduction; Exchange coupling and magnetism; Preparation and characterization of polyarylmethyl polyradicals; High-spin versus low-spin polyradicals; Diradicals; Triradicals; Tetraradicals
  • Diradical Anions and Diradical Dianions
Dimensions
unknown
Extent
1 online resource (347 p.)
Form of item
online
Isbn
9780080458199
Media category
computer
Media type code
c
Specific material designation
remote
System control number
  • (CKB)1000000000364842
  • (EBL)270124
  • (OCoLC)77236461
  • (SSID)ssj0000099120
  • (PQKBManifestationID)11132945
  • (PQKBTitleCode)TC0000099120
  • (PQKBWorkID)10002432
  • (PQKB)10917604
  • (MiAaPQ)EBC270124
  • (EXLCZ)991000000000364842

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