The Resource Alkyne‐Based Nanostructures on Silver Substrates, by Raphael Hellwig, (electronic resource)

Alkyne‐Based Nanostructures on Silver Substrates, by Raphael Hellwig, (electronic resource)

Label
Alkyne‐Based Nanostructures on Silver Substrates
Title
Alkyne‐Based Nanostructures on Silver Substrates
Statement of responsibility
by Raphael Hellwig
Creator
Author
Author
Subject
Language
eng
Summary
Acetylenic precursors are important reactants for creating carbon-based architectures via linkage reactions. While their capability of forming intermolecular bonds is well investigated in solution, very few systematic studies have been carried out to create alkyne-based nanostructures on metal substrates under ultra-high vacuum conditions. Synthesizing extended and regular carbon scaffolds requires a detailed knowledge of alkyne chemistry in order to control reaction pathways and limit unwanted side reactions. Using the bottom-up approach on metal surfaces, the author establishes protocols to fabricate regular architectures built up by the on-surface formation of selective organometallic and C-C bonds with thoughtfully designed alkyne-functionalized monomers. The structural and functional properties of the resulting organometallic and covalent nanostructures are characterized by means of scanning tunneling microscopy. The results open up new perspectives in the fields of heterogeneous catalysis and the on-surface synthesis of functional interfaces under mild reaction conditions
Member of
http://library.link/vocab/creatorName
Hellwig, Raphael
Dewey number
620.115
http://bibfra.me/vocab/relation/httpidlocgovvocabularyrelatorsaut
zFy_mDGtCx8
LC call number
  • QC176.8.N35
  • T174.7
Literary form
non fiction
Nature of contents
dictionaries
Series statement
Springer Theses, Recognizing Outstanding Ph.D. Research,
http://library.link/vocab/subjectName
  • Chemistry, Organic
  • Surfaces (Physics)
  • Nanoscale Science and Technology
  • Organometallic Chemistry
  • Surfaces and Interfaces, Thin Films
Label
Alkyne‐Based Nanostructures on Silver Substrates, by Raphael Hellwig, (electronic resource)
Instantiates
Publication
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
Introduction -- Experimental Methods -- Silver-bis-acetylide Wires -- Fabrication of Graphdiyne Nanowires -- Metal Alkynyl 22/7 Complexes -- Ho-Catalyzed Cyclotrimerization -- Conclusion and Outlook
Dimensions
unknown
Edition
1st ed. 2018.
Extent
1 online resource (132 pages)
Form of item
online
Isbn
9783030009977
Media category
computer
Media MARC source
rdamedia
Media type code
c
Other control number
10.1007/978-3-030-00997-7
Sound
unknown sound
Specific material designation
remote
System control number
  • (CKB)4100000007110539
  • (MiAaPQ)EBC5583556
  • (DE-He213)978-3-030-00997-7
  • (EXLCZ)994100000007110539
Label
Alkyne‐Based Nanostructures on Silver Substrates, by Raphael Hellwig, (electronic resource)
Publication
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
Introduction -- Experimental Methods -- Silver-bis-acetylide Wires -- Fabrication of Graphdiyne Nanowires -- Metal Alkynyl 22/7 Complexes -- Ho-Catalyzed Cyclotrimerization -- Conclusion and Outlook
Dimensions
unknown
Edition
1st ed. 2018.
Extent
1 online resource (132 pages)
Form of item
online
Isbn
9783030009977
Media category
computer
Media MARC source
rdamedia
Media type code
c
Other control number
10.1007/978-3-030-00997-7
Sound
unknown sound
Specific material designation
remote
System control number
  • (CKB)4100000007110539
  • (MiAaPQ)EBC5583556
  • (DE-He213)978-3-030-00997-7
  • (EXLCZ)994100000007110539

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