The Resource Catalytic oxidation : principles and applications, editors, R.A. Sheldon, R.A. van Santen

Catalytic oxidation : principles and applications, editors, R.A. Sheldon, R.A. van Santen

Label
Catalytic oxidation : principles and applications
Title
Catalytic oxidation
Title remainder
principles and applications
Statement of responsibility
editors, R.A. Sheldon, R.A. van Santen
Contributor
Subject
Genre
Language
  • eng
  • eng
Summary
This book consists of lectures presented by international authorities in the field, at a course on Oxidation Catalysis organized by the Dutch Research School in Catalysis at Rolduc in June 1994. The material covered spans the whole range of the subject from the fundamental principles of gas and liquid phase oxidations to reactor engineering for industrial processing. The use of catalytic oxidation in both bulk and fine chemicals manufacture and the different types of catalysis - heterogeneous-gas phase, homogeneous-liquid phase and heterogeneous-liquid phase - are discussed. In addition, a few
Cataloging source
MiAaPQ
Dewey number
541.393
Illustrations
  • illustrations
  • charts
Index
index present
Language note
English
LC call number
QD281.O9
LC item number
C38 1995
Literary form
non fiction
Nature of contents
  • dictionaries
  • bibliography
http://library.link/vocab/relatedWorkOrContributorName
  • Sheldon, Roger A
  • Santen, R. A. van
http://library.link/vocab/subjectName
  • Oxidation
  • Catalysis
Label
Catalytic oxidation : principles and applications, editors, R.A. Sheldon, R.A. van Santen
Instantiates
Publication
Copyright
Note
At head of title: NIOK, Netherlands Institute for Catalysis Research
Bibliography note
Includes bibliographical references and index
Carrier category
online resource
Carrier category code
cr
Content category
text
Content type code
txt
Contents
  • Preface; Contents; CATALYTIC OXIDATIONS: AN OVERVIEW; 1. Introduction; 2. Homogeneous Catalysis / Liquid phase; 3. Heterogeneous Catalysis / Gas Phase; 4. Propylene Oxide Manufacture: the Selectivity Problem; 5. Manufacture of Aromatic Acids; 6. Phenol Manufacture: Benzene versus Toluene as primary building block; 7. Caprolactam Manufacture: the Salt Issue; 8. Adipic Acid Production; 9. Major Trends in Chemicals Manufacture; 10. Mechanisms of metal-catalyzed oxidations; References; MECHANISM OF HETEROGENEOUS CATALYTIC OXIDATION; ABSTRACT; 1. ELECTROPHILIC AND NUCLEOPHILIC OXIDATION
  • 2. SELECTIVITY IN OXIDATION REACTIONS3. MECHANISM OF ELECTROPHILIC OXIDATION; 4. MECHANISM OF NUCLEOPHILIC OXIDATION; 5. MECHANISM OF THE OXIDATION OF ALKYLAROMATICS; 6. STRUCTURE SENSITIVITY; 7. SYNERGY OF CATALYTIC PROPERTIES IN OXIDE SYSTEMS; 8. THE DYNAMIC STATE OF OXIDE SURFACES; Further reading; HETEROGENEOUS OXIDATION CATALYSIS ON METALLIC OXIDES; ABSTRACT; 1. Introduction; 2. General features of oxidation catalysts and oxidation reaction^2; 2.1 Oxidation catalysts; 2.2 Oxygen species; 2.3 Selectivity and bond strength; 2.4 Reducibility of the cations
  • 2.5 Turn over number, turn over frequency3 Structure sensitivity of oxidation reactions on oxides; 4 Vanadyl pyrophosphate^15; 5.Iron phosphates and hydrophosphates^35-38; 6 Heteropolyoxometallates^41-42; 7 Zeolitic materials; 8 Synergy effect in multi component catalysts^45-50; 9 Supported oxide catalysts; 9.1 Molybdenum oxide supported on silica; 9.2 Vanadium oxide on TiO2 support; 9.3 Various oxides deposited on different oxide supports; 10 Conclusions; References; SELECTIVE CATALYTIC OXIDATION BY HETEROGENEOUS TRANSITION METAL CATALYSTS; ABSTRACT; 1. Introduction; 2. Reaction mechanisms
  • 2.1. Ethylene epoxidation by silver (3)2.2 Methanol oxidation; 2.3. Vinylacetate from ethylene and acetic acid; 2.4. CO oxidation; 3. The reactivity of transition metal surfaces for oxidation reactions; 3.1. Oxygen activation; 3.2. The activation of CH and OH bonds; 4. Summary; References; PARTIAL OXIDATION ON NOBLE METALS AT HIGH TEMPERATURES; ABSTRACT; 1. Catalytic Oxidation on Noble Metals; 2. Four Important Industrial Processes; 2.1 Nitric acid synthesis; 2.2 HCN synthesis; 2.3 Production of Syngas; 2.4 Production of olefins; 3. Understanding and Designing an Oxidation Process
  • 4. Reactor Simulation5. Mechanism and Kinetics of HCN Synthesis; 6. The Simplest Oxidation Reaction: H2+02; 7. Hydrocarbon Oxidation; 7.1 Syngas by Direct Oxidation of Methane; 7.2 Elementary Steps in Methane Oxidation; 7.3. Ethylene by Oxidative Dehydrogenation of Ethane; 7.4 Elementary Steps in C2H6 Oxidation; 8. Summary; 9. References; HIGH TEMPERATURE OXIDATION PROCESSES: OXIDATIVE COUPLING OF METHANE; ABSTRACT; 1. Introduction; 2. Coupling in the absence of catalyst; 3. Catalyst development; 3.1. Criteria; 3.2 Performance; 4. Catalytic routes; 5. Catalyst properties
  • 6. Chemical kinetics of catalytic coupling
Dimensions
unknown
Extent
1 online resource (393 p.)
Form of item
online
Isbn
9789814503884
Media category
computer
Media type code
c
Specific material designation
remote
System control number
  • (CKB)2550000001160062
  • (EBL)1561232
  • (OCoLC)863203987
  • (SSID)ssj0001040208
  • (PQKBManifestationID)12481199
  • (PQKBTitleCode)TC0001040208
  • (PQKBWorkID)10992285
  • (PQKB)10361998
  • (MiAaPQ)EBC1561232
  • (EXLCZ)992550000001160062
Label
Catalytic oxidation : principles and applications, editors, R.A. Sheldon, R.A. van Santen
Publication
Copyright
Note
At head of title: NIOK, Netherlands Institute for Catalysis Research
Bibliography note
Includes bibliographical references and index
Carrier category
online resource
Carrier category code
cr
Content category
text
Content type code
txt
Contents
  • Preface; Contents; CATALYTIC OXIDATIONS: AN OVERVIEW; 1. Introduction; 2. Homogeneous Catalysis / Liquid phase; 3. Heterogeneous Catalysis / Gas Phase; 4. Propylene Oxide Manufacture: the Selectivity Problem; 5. Manufacture of Aromatic Acids; 6. Phenol Manufacture: Benzene versus Toluene as primary building block; 7. Caprolactam Manufacture: the Salt Issue; 8. Adipic Acid Production; 9. Major Trends in Chemicals Manufacture; 10. Mechanisms of metal-catalyzed oxidations; References; MECHANISM OF HETEROGENEOUS CATALYTIC OXIDATION; ABSTRACT; 1. ELECTROPHILIC AND NUCLEOPHILIC OXIDATION
  • 2. SELECTIVITY IN OXIDATION REACTIONS3. MECHANISM OF ELECTROPHILIC OXIDATION; 4. MECHANISM OF NUCLEOPHILIC OXIDATION; 5. MECHANISM OF THE OXIDATION OF ALKYLAROMATICS; 6. STRUCTURE SENSITIVITY; 7. SYNERGY OF CATALYTIC PROPERTIES IN OXIDE SYSTEMS; 8. THE DYNAMIC STATE OF OXIDE SURFACES; Further reading; HETEROGENEOUS OXIDATION CATALYSIS ON METALLIC OXIDES; ABSTRACT; 1. Introduction; 2. General features of oxidation catalysts and oxidation reaction^2; 2.1 Oxidation catalysts; 2.2 Oxygen species; 2.3 Selectivity and bond strength; 2.4 Reducibility of the cations
  • 2.5 Turn over number, turn over frequency3 Structure sensitivity of oxidation reactions on oxides; 4 Vanadyl pyrophosphate^15; 5.Iron phosphates and hydrophosphates^35-38; 6 Heteropolyoxometallates^41-42; 7 Zeolitic materials; 8 Synergy effect in multi component catalysts^45-50; 9 Supported oxide catalysts; 9.1 Molybdenum oxide supported on silica; 9.2 Vanadium oxide on TiO2 support; 9.3 Various oxides deposited on different oxide supports; 10 Conclusions; References; SELECTIVE CATALYTIC OXIDATION BY HETEROGENEOUS TRANSITION METAL CATALYSTS; ABSTRACT; 1. Introduction; 2. Reaction mechanisms
  • 2.1. Ethylene epoxidation by silver (3)2.2 Methanol oxidation; 2.3. Vinylacetate from ethylene and acetic acid; 2.4. CO oxidation; 3. The reactivity of transition metal surfaces for oxidation reactions; 3.1. Oxygen activation; 3.2. The activation of CH and OH bonds; 4. Summary; References; PARTIAL OXIDATION ON NOBLE METALS AT HIGH TEMPERATURES; ABSTRACT; 1. Catalytic Oxidation on Noble Metals; 2. Four Important Industrial Processes; 2.1 Nitric acid synthesis; 2.2 HCN synthesis; 2.3 Production of Syngas; 2.4 Production of olefins; 3. Understanding and Designing an Oxidation Process
  • 4. Reactor Simulation5. Mechanism and Kinetics of HCN Synthesis; 6. The Simplest Oxidation Reaction: H2+02; 7. Hydrocarbon Oxidation; 7.1 Syngas by Direct Oxidation of Methane; 7.2 Elementary Steps in Methane Oxidation; 7.3. Ethylene by Oxidative Dehydrogenation of Ethane; 7.4 Elementary Steps in C2H6 Oxidation; 8. Summary; 9. References; HIGH TEMPERATURE OXIDATION PROCESSES: OXIDATIVE COUPLING OF METHANE; ABSTRACT; 1. Introduction; 2. Coupling in the absence of catalyst; 3. Catalyst development; 3.1. Criteria; 3.2 Performance; 4. Catalytic routes; 5. Catalyst properties
  • 6. Chemical kinetics of catalytic coupling
Dimensions
unknown
Extent
1 online resource (393 p.)
Form of item
online
Isbn
9789814503884
Media category
computer
Media type code
c
Specific material designation
remote
System control number
  • (CKB)2550000001160062
  • (EBL)1561232
  • (OCoLC)863203987
  • (SSID)ssj0001040208
  • (PQKBManifestationID)12481199
  • (PQKBTitleCode)TC0001040208
  • (PQKBWorkID)10992285
  • (PQKB)10361998
  • (MiAaPQ)EBC1561232
  • (EXLCZ)992550000001160062

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