The Resource Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands, by Priyabrata Ghana, (electronic resource)

Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands, by Priyabrata Ghana, (electronic resource)

Label
Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands
Title
Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands
Statement of responsibility
by Priyabrata Ghana
Creator
Author
Author
Subject
Language
eng
Summary
This book explores the development of the first open-shell heavier tetrylidyne complexes featuring a tetrel-centered unpaired electron, and unprecedented metallatetrylidynes containing a multiply-bonded, linear-coordinated single heavier tetrel atom embedded between two metal centers. The chemistry of compounds featuring triple bonds of the heavier Group-14 elements Si–Pb with transition metals is a very challenging research area, which combines modern molecular main-group element with transition-metal chemistry, and is of fundamental importance for the understanding of chemical bonding. During the last 15 years, the research in this area has witnessed considerable progress in isolating a series of closed-shell tetrylidyne complexes. However, despite numerous attempts, open-shell tetrylidyne complexes and heavier group 14 element congeners of metallacarbynes and carbide complexes remained inaccessible. In this book, readers will find more about the synthesis, full characterization and reactivity studies of these novel complexes that uncovered a plethora of exceptional products, including a novel m3-silicido complex, the first dimetallasilacumulene with a linear, two-coordinated single silicon atom and the first compounds of planar tetracoordinated silicon (ptSi) (Anti-van’t Hoff-Le Bell Silicon). Readers will also learn about the isolation and full characterization of the first room-temperature stable disilavinylidene, a silicon analogue of the very reactive vinylidenes (R2C=C:), and the first intermetallic plumbylidyne ligand transfer reactions.
Member of
http://library.link/vocab/creatorName
Ghana, Priyabrata
Dewey number
541.2242
http://bibfra.me/vocab/relation/httpidlocgovvocabularyrelatorsaut
f-K6BZbYmso
LC call number
QD410-412.5
Literary form
non fiction
Nature of contents
dictionaries
Series statement
Springer Theses, Recognizing Outstanding Ph.D. Research,
http://library.link/vocab/subjectName
  • Chemistry, Organic
  • Chemistry, inorganic
  • Spectroscopy
  • Organometallic Chemistry
  • Inorganic Chemistry
  • Spectroscopy/Spectrometry
Label
Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands, by Priyabrata Ghana, (electronic resource)
Instantiates
Publication
Bibliography note
Includes bibliographical references
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
Introduction -- Closed shell heavier tetrylidyne complexes of group 6 metals -- Open-shell heavier tetrylidyne complexes of group 6 transition metals -- Germylidyne mediated C–C coupling reaction of isonitriles – formation of an N-heterocyclic germylene -- A new method for the synthesis of manganese tetrylidyne complexes -- An open-shell manganese stannylidyne comprising of a tin-centered unpaired electron -- μ-Ylido complexes -- Chemistry of the metallatetrylidyne complexes -- Plumbylidyne transfer reaction -- Access to the first NHC-stabilized disilavinylidene -- Summary and Outlook -- Experimental Section
Dimensions
unknown
Edition
1st ed. 2019.
Extent
1 online resource (354 pages).
Form of item
online
Isbn
9783030026257
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Other control number
10.1007/978-3-030-02625-7
Sound
unknown sound
Specific material designation
remote
System control number
  • (CKB)4100000007205011
  • (MiAaPQ)EBC5614193
  • (DE-He213)978-3-030-02625-7
  • (EXLCZ)994100000007205011
Label
Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands, by Priyabrata Ghana, (electronic resource)
Publication
Bibliography note
Includes bibliographical references
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
Introduction -- Closed shell heavier tetrylidyne complexes of group 6 metals -- Open-shell heavier tetrylidyne complexes of group 6 transition metals -- Germylidyne mediated C–C coupling reaction of isonitriles – formation of an N-heterocyclic germylene -- A new method for the synthesis of manganese tetrylidyne complexes -- An open-shell manganese stannylidyne comprising of a tin-centered unpaired electron -- μ-Ylido complexes -- Chemistry of the metallatetrylidyne complexes -- Plumbylidyne transfer reaction -- Access to the first NHC-stabilized disilavinylidene -- Summary and Outlook -- Experimental Section
Dimensions
unknown
Edition
1st ed. 2019.
Extent
1 online resource (354 pages).
Form of item
online
Isbn
9783030026257
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Other control number
10.1007/978-3-030-02625-7
Sound
unknown sound
Specific material designation
remote
System control number
  • (CKB)4100000007205011
  • (MiAaPQ)EBC5614193
  • (DE-He213)978-3-030-02625-7
  • (EXLCZ)994100000007205011

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